Joining Nathan Adrian, Michael Phelps, and Ryan Lochte, Jones ran the third leg for USA, which finished in second place with a time of 3:10:38. France came away with the Gold, posting a time of 3:09:93.
Jones and the USA won the gold medal in the same event in 2008.
The 6-foot-5 swimmer will now participate in the two individual events that he will represent the USA in, the 50-meter and 100-meter freestyle. Jones was tabbed "USA's fastest swimmer" after winning the 50-meter freestyle at the USA Olympic trials.
The 100-meter heats begin tomorrow with the final taking place on Wednesday. The 50-meter freestyle heats are on Thursday with the final being held on Friday.